- His wife, Shirlie Kemp, was a back-up singer of the band Wham! and was one-half of the duo Pepsi & Shirlie.
- He played bass in the 1980s pop band Spandau Ballet. His older brother, Gary Kemp, was the guitarist, synthesizer player and songwriter. His other bandmates were Tony Hadley, John Keeble and Steve Norman.
- He has a metal plate in his head due to a brain tumor that was removed, not due to a motorcycle crash as is believed by some.
- He has three kidneys while his brother Gary only has one.
- He was introduced to his wife, Shirlie Kemp by singer George Michael. Shirlie had been one of his backing singers and remained a close friend.
- He and his brother Gary made their acting debuts in a 1972 episode of the BBC's Jackanory (1965) series.
- He has his own production company, Black & Blue Films.
- He was a guest call taker for the phone lines of the donations to The Prince's Trust 30th Birthday: Live (2006).
- He has a daughter, Harley Moon Kemp (born August 19, 1989) and a son Roman Kemp (born January 28, 1993), with his wife Shirlie Kemp.
- He considers "Through the Barricades" to be Spandau Ballet's best song.
- He advocated Queen as the world's greatest ever band for his appearance on Live (2010) and argued that Led Zeppelin are overrated.
- He is the ex brother-in-law of Sadie Frost.
- His EastEnders (1985) character Steve Owen's wedding to Mel Healy (Tamzin Outhwaite), Episode #1.2077 (2001), is ranked #8 in "The 50 Greatest EastEnders (1985) Weddings of All Time" (2010).
- He was ranked #32 in The 100 Greatest EastEnders (1985) Characters of All Time for his performance as Steve Owen (2015).
- He has a pin in his arm.
- He announced in July 2001 that he was leaving EastEnders (1985) when his contract ran out in April 2002.
- He trained at Anna Scher Drama School from age 8 with his brother Gary.
- Made his directing debut in Stalker and awarded Best Director at the British Horror Film Festival.
- He was ranked #29 in the 100 Greatest EastEnders (1985) Characters of All Time for his performance as Steve Owen (2010).
- He is one of seven EastEnders (1985) actors to have won a Best Actor Award at the British Soap Awards; the others are Ross Kemp, Joe Absolom, Shane Richie, Robert Kazinsky, Scott Maslen and Adam Woodyatt.
- Trained at Anna Scher Drama School at 8.
- Made his acting debut in Jackanory in 1872 with his brother.
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