- Cousin of actress Tamzin Outhwaite.
- Became a father for the 1st time at age 33 when his wife Holly Willoughby gave birth to their son Harry James Baldwin on 12 May 2009.
- Became a father for the 3rd time at age 38 when his wife Holly Willoughby gave birth to their son Chester William Baldwin on 29 September 2014.
- Became a father for the 2nd time at age 35 when his wife Holly Willoughby gave birth to their daughter Belle Baldwin on 20 April 2011.
- Older brother of James William (1978-2004), Dominic Anthony (b. 1980) and Francesca Maria Baldwin (b. 1983).
- Son of Peter William (1946-1986) and Sandra Maria (née Santi) Baldwin (b. 1949).
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