- TV commercial for charity association Planet Ark (Australia, 2002)
- Performed "Dare to Dream" with John Farnham during the Sydney Olympic Games opening ceremony on Friday, 15th September, 2000. On the previous night she ran with the Olympic Torch around the world-famous Sydney Opera House, eventually handing the Flame over to Australian tennis champion Patrick Rafter.
- As a singer she has recorded hundreds of records. The following is a list of CD albums she has recorded, not including compilations: - "If Not For You" - "Olivia Newton-John" - "Let Me Be There" - "Come On Over" - "Clearly Love" - "Making a Good Thing Better" - "Have You Never Been Mellow" - "Don't Stop Believin'" - "Long Live Love" - "Totally Hot" - "Grease (1978) Original Motion Picture Soundtrack" - "Xanadu (1980) Original Motion Picture Soundtrack" - "Physical" - "Two of a Kind (1983) Original Motion Picture Soundtrack" - "Soul Kiss" - "The Rumour" - "Gaia" - "Warm and Tender" - "It's My Party (1996) Original Motion Picture Soundtrack" - "Sordid Lives (2000) Original Motion Picture Soundtrack" - "Highlights from the Main Event" Compilations include: - "Greatest Hits" - "Greatest Hits Volume 2" - "Greatest Hits Volume 3" - "Back to the Basics" - "Magic" - "The Singles" - "Olivia" - "Great" - "Christmas Collection" She also did a Christmas CD with Vince Gill called "'Tis the Season" and her last all-new studio CD was "Back With a Heart".
- Released a CD of duets entitled "(2)"
- Print ads for Kellogg's Smart Start cereal (2004).
- CD: "Warm and Tender" (USP)
- Appeared in Michael Jackson's "Liberian Girl" music video
- (2010) Appeared in an infomercial, hosted by Chuck Norris, Gena O'Kelly, Christie Brinkley, for the "Total Gym" fitness program.
- (2012) Album, with John Travolta: "This Christmas".
- (2013) Hostess of an infomercial for TriVita's "Zamu Gold" wellness drink. Also appearing is husband, Amazon John Easterling.
- (2015) Music Video "You Have to Believe"
- (2016) Album, with Amy Sky and Beth Nielsen Chapman: "Liv On".
- (2019) Book: "Don't Stop Believin' ". ISBN: 1982122242
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